You have to Center (either For Success or Against Penalties per the rules on MITS, 73), which is a Free Action.
You can only perform one Free Action per phase unless you have Multi-Task, but I'd argue that to get the second benefit requires a second type of Centering (Dance + Singing, for example).
But anyway, it only applies to the first two shots because each use of Adept Centering applies to one Success Test.