Wards cannot be layered or overlap in the same area of astral space. However, there are disagreements as to whether a ward is a 'field' or a 'wall'. My personal reading of things is that it acts essentially like a wall, or shell, given that, once you are past that outer wall, there is no impairment as there would be if it was some kind of suppressive field. Therefore, you can have wards within eachother, so long as they do not occupy the same area of astral space. In other words, the inner ward cannot be touching any part of the outer ward's wall. The example I would use is a ward around a research lab to keep out astral spies, and a second, heavier ward around the high security wing, to keep intruders out (or to keep awakened test subjects in). So long as the two wards do not touch in astral space, you're fine.
But as I said, there are disagreements on whether the ward is a field or wall, and it has never been made clear in the books.